In an extensive study, Jeffrey C. Everts and Miha Ravnik from the Faculty of Mathematics and Physics at University of Ljubljana and the Department F5 of Jožef Stefan Institute examined the details of the coupling of ions and singular topological defects in complex nematic fluids (Phys. Rev. X 2021). The authors showed that topological defects in nematic electrolytes could perform as areas for local separation of electric charge, forming electrically charged cores of defect and in selected geometries also electrical multi-layers. These charge distribution are generalizations of electrical double layers known in isotropic electrolytes. In particular, they show that ions couple very efficiently with the defect cores through the mechanism of ionic solubility, and with the surrounding orientation field deformations through the mechanism of flexoelectricity. The work is a significant contribution towards understanding the electrostatic mechanisms in complex soft matter.